碘酸钚(IV)是一种无机化合物,化学式为Pu(IO3)4,它在540 °C以上分解为二氧化钚[3]。它可以在硝酸钚(IV)和碘酸反应中生成,但这种方法不能得到纯净的产物;[3]另一种制备方法是硝酸钚或氯化钚和碘酸钾及稀硝酸反应。[4]它可以以四方晶系结晶,空间群P42/n。[2]
参考文献[编辑]
- ^ Travis Henry Bray. Crossroads and Terminations in Transuranium Chemistry. Auburn University, 2008.
- ^ 2.0 2.1 Travis H. Bray, Jie Ling, Eun Sang Choi, James S. Brooks, James V. Beitz, Richard E. Sykora, Richard G. Haire, David M. Stanbury, and Thomas E. Albrecht-Schmitt. Critical Role of Water Content in the Formation and Reactivity of Uranium, Neptunium, and Plutonium Iodates under Hydrothermal Conditions: Implications for the Oxidative Dissolution of Spent Nuclear Fuel. Inorg. Chem. 2007, 46, 9, 3663–3668. doi:10.1021/ic070170d
- ^ 3.0 3.1 Dawson, J. K.; Elliott, R. M. The thermogravimetry of some plutonium compounds. Atomic Energy Research Estab. (Gt. Brit.), 1957.
- ^ Sklyarenko, I. S.; Chubukova, T. M. Thermogravimetry in analytical chemistry. IV. Thermogravimetric study of plutonium (IV) iodate. Zhurnal Analiticheskoi Khimii, 1963. 18 (4): 492-495. ISSN 0044-4502.