二十四碳化钾是一种石墨插层化合物,化学式为KC24。它可由八碳化钾和石墨在350~450 °C共热反应制得,[2]或由钾和石墨在真空中于350 °C反应得到。[1]它在Co(C2H4)(PMe3)3催化下和锂在戊烷中反应,可以得到Li2.67KC24。[3]
参考文献[编辑]
- ^ 1.0 1.1 Ichikawa, Masaru; Inoue, Yukio; Tamaru, Kenzi. Catalytic hydrogenation of benzene by graphite-potassium lamellar compounds C8K and C24K. Journal of the Chemical Society, Chemical Communications (1972), (16), 928-929. doi:10.1039/C39720000928.
- ^ Akuzawa, Noboru; Kunihashi, Yoji; Sato, Yuki; Tsuchiya, Ken-ichi; Matsumoto, Rika. Effect of sorbed molecules on the resistivity of alkali metal-graphite intercalation compounds. Journal of Solid State Chemistry (2007), 180(3), 894-901. doi:10.1016/j.jssc.2006.12.019.
- ^ Klein, H. F.; Dreisbach, M.; Gass, M.; Cordier, G. Saturation intercalation - preparation of first stacked lithium/potassium graphitides. Materials Science Forum (1992), 91-93: 35-40. doi:10.4028/www.scientific.net/MSF.91-93.35.
拓展阅读[编辑]
- Shioyama, Hiroshi. The reaction of potassium-graphite intercalation compounds with halogens(日語). Tanso, 2002. 203. 120-122. ISSN 0371-5345.
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| 稀有氣體、IA、IIA | |
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| 硼族、碳族 | |
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| 氮族 | |
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| 氧族 | |
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| 卤素、拟卤素 | |
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| 副族金属 | |
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| 有机酸盐 | |
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