Mission Start | Mission End | Name | Notes |
1492 | 1509 | Gutierre Gómez de Fuensalida | Ambassador to the Holy Roman Empire (House of Habsburg) |
| | | |
1564 | 1578 | Francisco Hurtado de Mendoza | Ambassador to the Holy Roman Empire |
1578 | 1581 | Juan de Borja y Castro | Ambassador to the Holy Roman Empire |
1581 | 1608 | Guillem de Santcliment | Ambassador to the Holy Roman Empire |
1608 | 1617 | Baltasar de Zúñiga y Velasco | Ambassador to the Holy Roman Empire |
| | | |
1622 | 1622 | Diego Sarmiento de Acuña | 1st Count of Gondomar |
| | | |
1632 | 1640 | Sancho de Monroy y Zúñiga | 1st Marquess of Castañeda |
1640 | 1640 | Francisco de Melo | - |
1642 | 1644 | Manuel de Moura y Corte-Real | 1st Marquess of Castañeda |
1700 | 1700 | Francisco Moles | - |
1700 | 1725 | Vacant | Interruption of diplomatic relations between Austria and Spain due to the War of Spanish Succession |
1725 | 1725 | Juan Guillermo Ripperdá | 1st Duke of Ripperdá; Treaty of Vienna |
1727 | 1728 | Baluard de Bournonville (fr) | - |
1728 | 1731 | José de Viana y Eguiluz | - |
1731 | 1733 | James Fitz-James Stuart | 2nd Duke of Berwick |
1734 | 1737 | Vacant | Interruption of diplomatic relations between Austria and Spain due to the War of Polish Succession |
1737 | 1738 | Pedro de Cebrián y Agustín | 5th Count of Fuenclara |
1738 | 1741 | José Carpintero | - |
1741 | 1748 | Vacant | Interruption of diplomatic relations between Austria and Spain due to the Austrian War of Succession |
1750 | 1754 | Antonio de Azlor y Marimón | - |
1755 | 1760 | Alonso Verdugo y Castilla | 3rd Count of Torrepalma |
1760 | 1777 | Demetrius O'Mahony | - |
1777 | 1779 | Domingo de Iriarte | Secretary |
1779 | 1785 | Vicente Manrique de Zúñiga | 13th Count of Altamira |
1786 | 1794 | José Agustín Llano y de la Quadra | 1st Marquess of Llano |
1814 | 1815 | Pedro Gómez Labrador | Marquess of Labrador; Spanish representative at the Congress of Vienna |
1893 | 1895 | Juan Valera y Alcalá-Galiano | - |
1936 | 1938 | Eduardo García Comín | - |
1936 | 1938 | Juan Schwartz Díaz-Flores | - |
| | | |
| 1956 | Luis de Urquijo y Landecho | 2nd Marquess of Bolarque |
1956 | 1964 | José Sebastián de Erice y O'Shea | - |
1964 | 1965 | Segismundo Royo Villanova y Fernández-Cavada | - |
1965 | 1967 | Antonio de Luna García | - |
1967 | 1970 | Joaquín Buxó-Dulce de Abaigar | Marquess of Castellflorite |
1970 | 1974 | Miguel María de Lojendio Irure | - |
1974 | 1976 | Laureano López Rodó | - |
1976 | 1981 | Juan Manuel Castro-Rial y Canosa | - |
1981 | 1985 | Juan Luis Pan de Soraluce y Olmos | Count of San Román |
1985 | 1991 | Jesús Núñez Hernández | - |
1991 | 1996 | Miguel Ángel Ochoa Brun | - |
1996 | 2000 | Ricardo Díez-Hochleitner Rodríguez | - |
2000 | 2004 | Raimundo Pérez-Hernández y Torra | - |
2004 | 2008 | Juan Manuel de Barandica y Luxán | - |
2008 | 2010 | Josep Maria Pons Irazazábal | - |
2010 | 2013 | Yago Pico de Coaña y de Valicourt | - |
2013 | 2017 | Alberto Carnero Fernández | Evo Morales grounding incident |
2017 | 2020 | Juan Sunyé Mendía | - |
2020 | 2024 | Cristina Fraile Jiménez de Muñana |
2024 | Incumbent | María Aurora Mejía Errasquín[1] |